MDCAT CHEM-CARBOXYLIC ACIDS & MACROMOLECULES (SMART INSTITUTE)

01-Which of the following is not carboxlic acid ?
CnH2n+1COOH
CnH2n+1OH
CnH2nO2
RCOOH
02-If methyl group of propane replaced by carboxylic resulting molecule is
Oxalic acid
Acetic acid
Malonic acid
All
03-Which of the following is un saturated aliphatic organic acid
Malic acid
Terephthalic acid
Phthalic acid
Adipic acid
04-Pentanoic acid is
Maleic acid
Glutamic acid
Adipic acid
Valeric acid
05-Wich one is carboxylic acid
Carbolic acid
Picric acid
Carbonic acid
Palmitic acid
06-Which one is not fatty acid
Palmitic acid
Stearic acid
Phthalic acid
Oleic acid
07-Organic acid which cannot obtained by hydrolysis of fats
Succinic acid
Acetic acid
Butyric acid
Propionic acid
08-Isobutyric acid also written as
2-Propanoic acid
2-Methylpropanoic acid
2-Ethylpropanoic acid
Ethanedioic acid
09-The compound that first isolated by red ants ;
Acetic acid
Butyric acid
Formic acid
Valeric acid
10-By oxidation of which compound carboxlic acid cannot be obtained'
2-Methyl,2-propanol
1-Butanol acid
2-Butanol
3-prropanol
11 Which of the following compound cannot oxidized to carboxylic acid by mild oxidizing agent;
Ethanol
Propanone
Ethanal
Propionaldehyde
12- A compound oxidized to x, by further oxidation of x if resulting compound is butyric acid ,starting compound can be ;
Butanol
Butanoic acid
Butanone
All of these
13-Alkane nitriles with which type of acid gives organic acids
Organic
Phenol
Alcohol
Mineral
14-Hybridization of functional carbon , change from .to.....when converting to carboxylic
Sp to sp
Sp to sp2
Sp to sp3
Sp2 to sp2
15-Metalic cyanides alkyl cyanides in the presence of
Acid
Water
Base
Alcohol
16- Gas released by acid hydrolysis of alkyl nitriles
NO2
NH3
CO2
H2
17-Ethyl cyanide boiled with HCI in the presence of water gives
Methanoic acid
Propanoic acid
Ethanoic acid
Butanoic acid
18- Which member from simple, primary alkyl halides gives butyric acid by acid hydrolysis
1st
3rd
2nd
4th
19-Oxidation of 2-pentanone by strong oxidizing agents gives
Methanoic acid, ethanoic acid
Propanoic acid, ethanoic acid
Ethanoic acid butanoic acid
Butanoic acid, methanoic acid
20-A molecule is oxidized to simple aliphatic carboxylic acid if the molecule gives silver mirror but do not behave as an acid, identify the molecule
Butanol
Propanoic acid
Ethanol
Propanal
21-Which metal do not release hydrogen from valeric acid
Mg
Ca
K
Pb
22-Potassium carbonate decomposed by acetic acid release a gas, the nature of gas is
Basic
Netural
Acidic
Unpredictable
23-which of the following cannot show acidic nature of carboxylic acids
Alkali metals
Alkali metal carbonates
Alkaline earth metals
All
24-carboxylic acid decompose bicarbonates with
Effervescence
Esterification
Hydrogen
Reaction dont proceed
25-which group of carboxylic acid is active for reaction alkali carbonates
H-atom
Carbonyl group
Hydroxyl group
Carboxylic group
26-which reaction can be used in artificial juices formation with carboxylic acids
Hydration
Esterification
Hydrolysis
Salt format
27- the addition of ethyl alcohol in protonated acetic acid is
Electrophilic
Substitution
Nucleophilic
Oxidation
28-Ethyl alcohol reacts with which to give a product having pineapple flavor
Acetic acid
Valeric acid
Formic acid
Butyric acid
29-Which one is benzyl acetate
C6H5CH2COOH
C6H5COOC6H5
C6H5COOH3
CH3(OH2)2COOC2H5
30-Benzyl alcohol and acetic acid give a compound with......fargrance
Banana
Pineapple
Apricot
Jasmine
31-Esterification is a reaction
Condensation
Neutralization
Elimination
All
32-Ammonium acetate converts to acetamide by
Cooling
Heating
Dehydration
Both b and c
33-Which of following do not give acetamide when react with ammonia
Carboxylic acid
Acid chloride
Acid anhydride
Alkyl nitrite
34-Which of the following represent acid amide
CH3COONH2
CH3COCL
CH3CONO2
CH3CONH2
35-Carboxylic acid derivative least reactivity is
Ester
Acid anhydride
Acid amide
Acid halid
36-Which sequence of groups replace OH of carboxylic acid to halides ,esters and amides respectively
OH,X,NH2
X,OR,NH2
NH2,H,X
X,OR,NO2
37-Which one do not convert acid to acid halide
CL2
SOCL2
PCL5
PCL3
38-Which gas release during acid halide formation with the help of thionyl chloride
CO2
NO
SO2
SO3
39-Which factor decrease strength of carboxylic acid
Branching
Chargeof proton
Electron donation group
All
40-Strongest acid among following is
CH3CH2COOH
CH3CHCLCOOH
CH3CCL2COOH
CH3CH(NH2)COOH
41-Acetic acid (ethanoic acid )can be preparedby ethanol under
Oxidizing condition
Reducing condition
Redox condition
7.0 pH condition
42-Ethanoic acid manufactured through ethanol involves the use of
Acidified potassium dichromate
Ammonical silver nitrate
Both 'A'and 'C'
Fehling 's solution
43-If ethanoic acid is to be prepared by hydrolysis of alkane nitriles, which of the following can be the reagent to be hydrolyzed
CH3CN
CH3CH2CN
HCN
NACN+HCL
44-Hydrolysis of alkane nitriles for preparing carboxylic acids requires
Acidic conditions
Alkaline conditions
Any of the above
Both are simultaneously necessary
45-Hydrolysis of CH3CH2CN will synthesize
Ethanoic acid
Propanoic acid
Methanoic acid
Glutamic acid
46-The production of acid amide involves the reaction of ethanoic acid with
Amine
Ammonia
Amino acid
All of these
47-Which of the following can the reagent to product acetyl chloride from ethanoic acid
Thionyl chloride
PCL5
NACL
Both ,A,and
48-During the formation of an acetyl chloride from ethanoic acid ,what actually happens
Displacement of the H from the acid by CL
Displacement of the OH from the acid by CL
Attachment of CL with the carbonyl carbon
None of these
49-During the formation of an ester from acetic acid , what actually happens
Displacement of the H from the acid by CL
Displacement of the OH from the acid by OCH3
Attachment of OCH3 with the carbonyl oxygen
Displacement of the H from the acid by OCH3
50-During the formation of an acid amide from ethanoic acid ,what actually happens
Displacement of the H from the acid by Cl
Displacement of the OH from the acid by NH2
Attachment of NH2 with the carbonyl oxygen
Displacement of the H from the acid by NH2
51-The stronger acid among the following is
CL3CCOOH
CLCH2COOH
CL2CHCOOH
CH3COOH
52-If NaOH is added to an unknown organic compound and the reaction evolves ammonia, then this unknown organic compound is most likely to be
An ester
An acid amide
A carboxylic acid
An alkene
53-Organic acid (carboxylic acid )are considered as
Strong acids
Weak acid
Mild acid
Mineral acid
54-Pure organic acid are much
Weaker than chloro substituted acid s
Stronger than chloro substituted acid
Same strength as chloro substituted acid
None of these
55- The strength of the organic acids and chloro substituted acids is measured by Pk scale such that smaller value of PK corresponds to
Stronger acid
Weaker acid
Mild acid
Very weak acid
56-Alkane nitriles can be prepared by treating alkyl halide with
Alcohol
Alcoholic potassium cyanide
Potassium cyanide
Water
57-Ethanoic acid can be prepared by hydrolysis of
Methyl chloride
Ethane nitrile
Methane nitrile
Ethyl chloride
58-Carboxylic acid react with active metals (Na,K,and Mg) to from their salt and
H2O
CO2 only
H2O and CO2
H2 gas
59-Which pair can be used as a reactant for the preparation of acetyl chloride
CH3COOH,HCL
CH3COOH,PCL5
CH3COOH,SOCL2
Both 'B'and 'C'
60- For producing a carboxylic acid derivative .the addition of nucleophile to carboxylic group is always followed by displacement of
COOH group
OH group
H atom
Or
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